D. R. Hartree
Abstract
The methods of solution of the wave equation for a central field given in the previous paper are applied to various atoms. For the core electrons, the details of the interaction of the electrons in a single nk group are neglected, but an approximate correction is made for the fact that the distributed charge of an electron does not contribute to the field acting on itself (§2).
For a given atom the object of the work is to find a field such that the solutions of the wave equation for the core electrons in this field (corrected as just mentioned for each core electron) give a distribution of charge which reproduces the field. This is called the self-consistent field, and the process of finding it is one of successive approximation (§ 3).
Approximations to the self-consistent field have been found for He (§ 4), Rb+ (§ 5), Na+, Cl− (§ 9). For He the energy parameter for the solution of the wave equation for one electron in the self-consistent field of the nucleus and the other corresponds to an ionisation potential of 24·85 volts (observed 24·6 volts); this agreement suggests that for other atoms the values of the energy parameter in the self-consistent field (corrected for each core electron) will probably give good approximations to the X-ray terms (§4).
The most extensive work has been carried out for Rb+. The distribution of charge given by the wave functions in the self-consistent field is compared with the distribution calculated by other methods (§ 6). The values of X-ray and optical terms calculated from the self-consistent field show satisfactory agreement with those observed (§ 7).
The wave mechanical analogue of the case in which on the orbital model an internal and an external orbit of the same energy are possible is discussed (§ 8).
https://sci-hub.se/https://doi.org/10.1017/S0305004100011920
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